No, FEd2000 won't let you assign goalkeeper jerseys. Only 9 are used in FIFA 2000 (a bug of EA's!)
You can't assign special keeper jerseys for teams either...

Sorry!

I got a question for you about FEd and FIFA:
how many GK's kit can we have and is there a way to have a special GK's kit for a team?

To chau le:thanks again for such a great work, you are doing.
http://www.soccergaming.com/ubb/cool.gif